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Utilization of a Crown Ether/Amine‐Type Rotaxane as a Probe for the Versatile Detection of Anions and Acids by Thin‐Layer Chromatography
http://hdl.handle.net/10098/00028507
http://hdl.handle.net/10098/000285076b276fa9-3329-4679-82f3-1bc78e7c7a49
名前 / ファイル | ライセンス | アクション |
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bd10125751 (11.0 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-10-07 | |||||
タイトル | ||||||
タイトル | Utilization of a Crown Ether/Amine‐Type Rotaxane as a Probe for the Versatile Detection of Anions and Acids by Thin‐Layer Chromatography | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Utilization of a Crown Ether/Amine‐Type Rotaxane as a Probe for the Versatile Detection of Anions and Acids by Thin‐Layer Chromatography | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Company legal issue | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Ammonium compounds | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Ammonium paratungstate | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_1843 | |||||
資源タイプ | other | |||||
著者 |
Miyagawa, Shinobu
× Miyagawa, Shinobu× Kimura, Masaki× Kagami, Shin× Kawasaki, Tsuneomi× Tokunaga, Yuji |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A crown ether/amine‐type [2]rotaxane was synthesized and utilized as a probe for the detection of acids and anions. The addition of acids to the amine‐type [2]rotaxane solution generated corresponding crown ether/ammonium‐type [2]rotaxanes, which were purified by silica gel column chromatography as ammonium salts. The isolated yields of the [2]rotaxanes, possessing a variety of anions, depended on the acidity and polarity of the counter anions. The behaviours of the ammonium‐type [2]rotaxanes on thin‐layer chromatography (TLC) silica gel reflected the properties of the counter anions. The treatment of the amine‐type [2]rotaxane with acids afforded the corresponding ammonium‐type [2]rotaxanes bearing several different anions. The ammonium‐type [2]rotaxanes behaved similarly to the purified [2]rotaxanes on the TLC silica gel. Furthermore, we succeeded in the analysis of anions using mixtures of the amine‐type [2]rotaxane and salts in an appropriate solvent. We demonstrated the detection of anions by the combination of TLC and the utilization of the [2]rotaxane probe. | |||||
書誌情報 |
en : Chemistry An Asian Journal 巻 15, 号 19, p. 3044-3049, 発行日 2020-08-11 |
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出版者 | ||||||
出版者 | Wiley-VCH | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1861-4728 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1002/asia.202000746 | |||||
権利 | ||||||
権利情報 | copyright 2020 Wiley-VCH GmbH | |||||
権利 | ||||||
権利情報 | copyright 2020 Gale, Cengage Learning. All rights reserved. | |||||
著者版フラグ | ||||||
出版タイプ | AO | |||||
出版タイプResource | http://purl.org/coar/version/c_b1a7d7d4d402bcce | |||||
その他のID | ||||||
TD10125751 |