{"created":"2023-05-15T10:31:59.420941+00:00","id":28627,"links":{},"metadata":{"_buckets":{"deposit":"4edcfc26-6952-4b7f-87c8-fc826c203cc8"},"_deposit":{"created_by":15,"id":"28627","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"28627"},"status":"published"},"_oai":{"id":"oai:u-fukui.repo.nii.ac.jp:00028627","sets":["2403:2404"]},"author_link":["81094","81093","81095","81096","81092"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-08-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"19","bibliographicPageEnd":"3049","bibliographicPageStart":"3044","bibliographicVolumeNumber":"15","bibliographic_titles":[{},{"bibliographic_title":"Chemistry An Asian Journal","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A crown ether/amine‐type [2]rotaxane was synthesized and utilized as a probe for the detection of acids and anions. The addition of acids to the amine‐type [2]rotaxane solution generated corresponding crown ether/ammonium‐type [2]rotaxanes, which were purified by silica gel column chromatography as ammonium salts. The isolated yields of the [2]rotaxanes, possessing a variety of anions, depended on the acidity and polarity of the counter anions. The behaviours of the ammonium‐type [2]rotaxanes on thin‐layer chromatography (TLC) silica gel reflected the properties of the counter anions. The treatment of the amine‐type [2]rotaxane with acids afforded the corresponding ammonium‐type [2]rotaxanes bearing several different anions. The ammonium‐type [2]rotaxanes behaved similarly to the purified [2]rotaxanes on the TLC silica gel. Furthermore, we succeeded in the analysis of anions using mixtures of the amine‐type [2]rotaxane and salts in an appropriate solvent. We demonstrated the detection of anions by the combination of TLC and the utilization of the [2]rotaxane probe.","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley-VCH"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/asia.202000746","subitem_relation_type_select":"DOI"}}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"copyright 2020 Wiley-VCH GmbH"},{"subitem_rights":"copyright 2020 Gale, Cengage Learning. All rights reserved."}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1861-4728","subitem_source_identifier_type":"ISSN"}]},"item_10001_text_25":{"attribute_name":"その他のID","attribute_value_mlt":[{"subitem_text_value":"TD10125751"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_b1a7d7d4d402bcce","subitem_version_type":"AO"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Miyagawa, Shinobu","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kimura, Masaki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kagami, Shin","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawasaki, Tsuneomi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tokunaga, Yuji","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-10-07"}],"displaytype":"detail","filename":"bd10125751.pdf","filesize":[{"value":"11.0 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"bd10125751","url":"https://u-fukui.repo.nii.ac.jp/record/28627/files/bd10125751.pdf"},"version_id":"3f35f20d-432d-4511-b5de-9a30395cdfd9"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Company legal issue","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Ammonium compounds","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Ammonium paratungstate","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"other","resourceuri":"http://purl.org/coar/resource_type/c_1843"}]},"item_title":"Utilization of a Crown Ether/Amine‐Type Rotaxane as a Probe for the Versatile Detection of Anions and Acids by Thin‐Layer Chromatography","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Utilization of a Crown Ether/Amine‐Type Rotaxane as a Probe for the Versatile Detection of Anions and Acids by Thin‐Layer Chromatography"},{"subitem_title":"Utilization of a Crown Ether/Amine‐Type Rotaxane as a Probe for the Versatile Detection of Anions and Acids by Thin‐Layer Chromatography","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"15","path":["2404"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-10-07"},"publish_date":"2020-10-07","publish_status":"0","recid":"28627","relation_version_is_last":true,"title":["Utilization of a Crown Ether/Amine‐Type Rotaxane as a Probe for the Versatile Detection of Anions and Acids by Thin‐Layer Chromatography"],"weko_creator_id":"15","weko_shared_id":-1},"updated":"2023-05-15T12:09:07.919515+00:00"}